Period 2 is the first period in the periodic table from which
periodic trends can be drawn.
Period 1, which only contains two elements (
hydrogen and
helium), is too small to draw any conclusive trends from it, especially because the two elements behave nothing like other s-block elements. Period 2 has much more conclusive trends. For all elements in period 2, as the atomic number increases, the
atomic radius of the elements decreases, the
electronegativity increases, and the
ionization energy increases. Period 2 only has two
metals (lithium and beryllium) of eight elements, less than for any subsequent period both by number and by proportion. It also has the most number of nonmetals, namely five, among all periods. The elements in period 2 often have the most extreme properties in their respective groups; for example, fluorine is the most reactive
halogen, neon is the most inert
noble gas, and lithium is the least reactive
alkali metal. All period 2 elements completely obey the
Madelung rule; in period 2, lithium and beryllium
fill the 2s subshell, and boron, carbon, nitrogen, oxygen, fluorine, and neon
fill the 2p subshell. The period shares this trait with periods 1 and
3, none of which contain
transition elements or
inner transition elements, which often vary from the rule. and the first metal of any kind in the periodic table. At
standard temperature and pressure, lithium is a soft, silver-white, highly reactive
metal. With a
density of 0.564 g⋅cm−3, lithium is the lightest metal and the least dense solid element. Lithium is one of the few elements
synthesized in the
Big Bang. Lithium is the 31st most abundant element on earth, occurring in concentrations of between 20 and 70 ppm by weight, Lithium
salts are used in the pharmacology industry as
mood stabilising drugs. It also has one of the highest
melting points of all the
light metals. Beryllium's most common
isotope is 9Be, which contains 4 protons and 5 neutrons. It makes up almost 100% of all naturally occurring beryllium and is its only stable isotope; however
other isotopes have been synthesised. In ionic compounds, beryllium loses its two
valence electrons to form the cation, Be2+. Small amounts of beryllium were
synthesised during the
Big Bang, although most of it
decayed or reacted further to create larger nuclei, like carbon, nitrogen or oxygen. Beryllium is a component of 100 out of 4000 known
minerals, such as
bertrandite, Be4Si2O7(OH)2,
beryl, Al2Be3Si6O18,
chrysoberyl, Al2BeO4, and
phenakite, Be2SiO4. Precious forms of beryl are
aquamarine,
red beryl and
emerald. The most common sources of beryllium used commercially are beryl and bertrandite and production of it involves the
reduction of
beryllium fluoride with
magnesium metal or the
electrolysis of molten
beryllium chloride, containing some
sodium chloride as beryllium chloride is a poor
conductor of electricity. Sheets of beryllium are used in
X-ray detectors to filter out
visible light and let only X-rays through. Beryllium and beryllium compounds are classified by the
International Agency for Research on Cancer as
Group 1 carcinogens; they are carcinogenic to both animals and humans. Chronic
berylliosis is a
pulmonary and
systemic granulomatous disease caused by exposure to beryllium. Between 1% – 15% of people are sensitive to beryllium and may develop an inflammatory reaction in their
respiratory system and
skin, called chronic beryllium disease or
berylliosis. The body's
immune system recognises the beryllium as foreign particles and mounts an attack against them, usually in the lungs where they are breathed in. This can cause fever, fatigue, weakness, night sweats and difficulty in breathing.
Boron Boron (B) is the chemical element with atomic number 5, occurring as 10B and 11B. At standard temperature and pressure, boron is a
trivalent metalloid that has several different
allotropes.
Amorphous boron is a brown powder formed as a product of many chemical reactions.
Crystalline boron is a very hard, black material with a high melting point and exists in many
polymorphs: Two
rhombohedral forms, α-boron and β-boron containing 12 and 106.7 atoms in the rhombohedral unit cell respectively, and 50-atom
tetragonal boron are the most common. Boron has a density of 2.34−3. Boron's most common
isotope is 11B at 80.22%, which contains 5 protons and 6 neutrons. The other common isotope is 10B at 19.78%, which contains 5 protons and 5 neutrons. These are the only stable isotopes of boron; however
other isotopes have been synthesised. Boron forms covalent bonds with other
nonmetals and has
oxidation states of 1, 2, 3 and 4. Boron does not occur naturally as a free element, but in compounds such as
borates. The most common sources of boron are
tourmaline,
borax, Na2B4O5(OH)4·8H2O, and
kernite, Na2B4O5(OH)4·2H2O. However, high soil concentrations of over 1.0
ppm can cause necrosis in leaves and poor growth. Levels as low as 0.8 ppm can cause these symptoms to appear in plants particularly boron-sensitive. Most plants, even those tolerant of boron in the soil, will show symptoms of boron toxicity when boron levels are higher than 1.8 ppm. It is also used as a supplement for the prevention and treatment of osteoporosis and arthritis. At standard temperature and pressure, carbon is a solid, occurring in
many different allotropes, the most common of which are
graphite,
diamond, the
fullerenes and
amorphous carbon. In
mineralogy, the term is used to refer to
soot and
coal, although these are not truly amorphous as they contain small amounts of graphite or diamond. Carbon's most common isotope at 98.9% is 12C, with six protons and six neutrons. 13C is also stable, with six protons and seven neutrons, at 1.1%. Other
isotopes of carbon have also been synthesised. Carbon forms covalent bonds with other non-metals with an oxidation state of −4, −2, +2 or +4. and is the second
most abundant element in the human body by mass after oxygen, the third most abundant by number of atoms. There are an almost infinite number of compounds that contain carbon due to carbon's ability to form long stable chains of
C–C bonds. The simplest carbon-containing molecules are the
hydrocarbons, which contain carbon and hydrogen, It occurs naturally in form of two isotopes: nitrogen-14 and nitrogen-15. Many industrially important compounds, such as
ammonia,
nitric acid, organic nitrates (
propellants and
explosives), and
cyanides, contain nitrogen. The extremely strong bond in elemental nitrogen dominates nitrogen chemistry, causing difficulty for both organisms and industry in breaking the bond to convert the molecule into useful
compounds, but at the same time causing release of large amounts of often useful energy when the compounds burn, explode, or decay back into nitrogen gas. Nitrogen occurs in all living organisms, and the
nitrogen cycle describes movement of the element from air into the
biosphere and organic compounds, then back into the atmosphere. Synthetically produced
nitrates are key ingredients of industrial
fertilizers, and also key pollutants in causing the
eutrophication of water systems. Nitrogen is a constituent element of
amino acids and thus of
proteins, and of
nucleic acids (
DNA and
RNA). It resides in the
chemical structure of almost all
neurotransmitters, and is a defining component of
alkaloids, biological molecules produced by many organisms.
Oxygen Oxygen is the chemical element with atomic number 8, occurring mostly as 16O, but also 17O and 18O. Oxygen is the third-most common element by mass in the universe (although there are more carbon atoms, each carbon atom is lighter). It is highly electronegative and non-metallic, usually diatomic, gas down to very low temperatures. Only fluorine is more reactive among non-metallic elements. It is two electrons short of a full octet and readily takes electrons from other elements. It reacts violently with
alkali metals and
white phosphorus at room temperature and less violently with alkali earth metals heavier than magnesium. At higher temperatures it burns most other metals and many non-metals (including hydrogen, carbon, and sulfur). Many oxides are extremely stable substances difficult to decompose—like
water,
carbon dioxide,
alumina,
silica, and iron oxides (the latter often appearing as
rust). Oxygen is part of substances best described as some salts of metals and oxygen-containing acids (
nitrates,
sulfates,
phosphates,
silicates, and
carbonates). Oxygen is essential to all life. Plants and
phytoplankton photosynthesize carbon dioxide and water, both oxides, in the presence of sunlight to form
sugars with the release of oxygen. The sugars are then turned into such substances as cellulose and (with nitrogen and often sulfur) proteins and other essential substances of life. Animals especially but also fungi and bacteria ultimately depend upon photosynthesizing plants and phytoplankton for food and oxygen.
Fire uses oxygen to oxidize compounds typically of carbon and hydrogen to water and carbon dioxide (although other elements may be involved) whether in uncontrolled conflagrations that destroy buildings and forests or the controlled fire within engines or that supply electrical energy from turbines, heat for keeping buildings warm, or the motive force that drives vehicles. Oxygen forms roughly 21% of the Earth's atmosphere; all of this oxygen is the result of photosynthesis. Pure oxygen has use in medical treatment of people who have respiratory difficulties.
Excess oxygen is toxic. Oxygen was originally associated with the formation of acids—until some acids were shown to not have oxygen in them. Oxygen is named for its formation of acids, especially with non-metals. Some oxides of some non-metals are extremely acidic, like
sulfur trioxide, which forms
sulfuric acid on contact with water. Most oxides with metals are alkaline, some extremely so, like
potassium oxide. Some metallic oxides are amphoteric, like aluminum oxide, which means that they can react with both acids and bases. Although oxygen is normally a diatomic gas, oxygen can form an allotrope known as
ozone. Ozone is a triatomic gas even more reactive than oxygen. Unlike regular diatomic oxygen, ozone is a toxic material generally considered a pollutant. In the upper atmosphere, some oxygen forms ozone which has the property of absorbing dangerous ultraviolet rays within the
ozone layer. Land life was impossible before the formation of an ozone layer.
Fluorine Fluorine is the chemical element with atomic number 9. It occurs naturally in its only stable form 19F. Fluorine is a pale-yellow, diatomic gas under normal conditions and down to very low temperatures. Short one electron of the highly stable octet in each atom, fluorine molecules are unstable enough that they easily snap, with loose fluorine atoms tending to grab single electrons from just about any other element. Fluorine is the most reactive of all elements, and it even attacks many oxides to replace oxygen with fluorine. Fluorine even attacks silica, one of the favored materials for transporting strong acids, and burns asbestos. It attacks
common salt, one of the most stable compounds, with the release of chlorine. It never appears uncombined in nature and almost never stays uncombined for long. It burns hydrogen simultaneously if either is liquid or gaseous—even at temperatures close to absolute zero. It is extremely difficult to isolate from any compounds, let alone keep uncombined. Fluorine gas is extremely dangerous because it attacks almost all organic material, including live flesh. Many of the binary compounds that it forms (called fluorides) are themselves highly toxic, including soluble fluorides and especially
hydrogen fluoride. Fluorine forms very strong bonds with many elements. With sulfur it can form the extremely stable and chemically inert
sulfur hexafluoride; with carbon it can form the remarkable material
Teflon that is a stable and non-combustible solid with a high melting point and a very low coefficient of friction that makes it an excellent liner for cooking pans and raincoats. Fluorine-carbon compounds include some unique plastics. It is also used as a reactant in the making of toothpaste.
Neon Neon is the chemical element with atomic number 10, occurring naturally as three stable isotopes: 20Ne, 21Ne and 22Ne. Neon is a
monatomic gas. With a complete octet of outer electrons, it is highly resistant to electron removal and does not readily accept electrons, making it effectively inert. It is classified as one of the
noble gases. Although relatively scarce on Earth, neon is the fifth most abundant element in the universe, formed during the
alpha process in stars. On Earth it is obtained by
fractional distillation of liquid air, where it is present at about 18 ppm by volume in the atmosphere. Neon has no known biological role. The element is best known for its distinctive orange-red glow in low-pressure gas-discharge tubes and
neon advertising signs, first demonstrated in 1910 by
Georges Claude. Neon is also used in high-voltage indicators,
lightning arresters,
plasma screens,
cryogenic refrigeration (due to its low boiling point), and as a component in some lasers. ==Notes==