Six mineral types are defined by the EPA as "asbestos" including those belonging to the serpentine class and those belonging to the amphibole class. All six asbestos mineral types are known to be human
carcinogens. The visible fibers are themselves each composed of millions of microscopic "fibrils" that can be released by abrasion and other processes. Artificial Christmas snow, known as flocking, was previously made with asbestos. It was used as an effect in films including the scarecrows costume in
The Wizard of Oz; there is a rumor that it was used as snow in the poppy field, but it was actually
gypsum.
Serpentine group , London, 1941, nurses arrange asbestos blankets over an electrically heated frame to create a hood over patients to help warm them quickly.
Serpentine minerals have a sheet or layered structure, and produce curly fibers.
Chrysotile, CAS No. , is the only asbestos serpentine fiber. It is obtained from
serpentinite rocks which are common throughout the world. Its idealized
chemical formula is
Mg(
SiO)(
OH). Chrysotile is more flexible than amphibole asbestos and can be spun and woven into fabric. The most common use was corrugated asbestos cement roofing primarily for outbuildings, warehouses, and garages. It may also be found in sheets or panels used for ceilings and sometimes for walls and floors. Chrysotile has been a component in
joint compound and some plasters. Numerous other items have been made containing chrysotile including brake linings, fire barriers in fuseboxes, pipe insulation, floor tiles, residential shingles, and gaskets for high-temperature equipment. Chrysotile is often present in a wide variety of products and materials, including: • Chlor Alkali diaphragm membranes
used to make chlorine (currently in the US) •
Drywall and joint compound (including texture coats) •
Plaster • Gas mask filters throughout World War II until the 1960s for most countries; Germany and the USSR's Civilian issued filters up until 1988 tested positive for asbestos • Vinyl floor tiles, sheeting, adhesives • Roofing tars, felts, siding, and shingles • "
Transite" panels, siding, countertops, and pipes •
Popcorn ceilings, also known as acoustic ceilings •
Fireproofing •
Caulk • Industrial and marine
gaskets •
Brake pads and shoes • Stage curtains • Fire blankets • Cement pipework • Interior fire doors • Fireproof clothing for firefighters • Thermal pipe insulation • Filters for removing fine particulates from chemicals, liquids, and wine • Dental cast linings • HVAC flexible duct connectors •
Drilling fluid additives • Finishing tool handles in bookbinding In the European Union and Australia, it has been banned as a potential health hazard and is no longer used at all. File:Arcon mk post-war pre-fab.jpg|Example of
asbestos cement siding and lining on a post-war temporary house in
Yardley, Birmingham. Nearly 40,000 of these structures were built between 1946 and 1949 to house families. File:Heat-resistant asbestos glove.jpg|An asbestos glove File:M60 machine gun barrel change DF-ST-90-04667.jpg| The
M60 machine gun crew member responsible for a hot barrel change was issued protective asbestos gloves to prevent burns to the hands File:AsbestosHeatSpreaderForCooking.jpg|A household heat spreader for cooking on gas stoves, made of asbestos (probably 1950s; "" is French for "pure asbestos") File:Asbesthaltige Flachdichtungen.jpg|Gasket, containing nearly unbound asbestos File:Asbestos pipe 'REAL ASBESTOS BEST QUALITY'.jpg|Asbestos pipe for tobacco smoking from Belgium, with inscription "Real asbestos best quality"
Amphibole group Amphibole class fibers are needle-like.
Amosite,
crocidolite,
tremolite,
anthophyllite and
actinolite are members of the amphibole class.
Amphiboles including
amosite (brown asbestos) and
crocidolite (blue asbestos) were formerly used in many products until the early 1980s.
Tremolite asbestos constituted a contaminant of many if not all naturally occurring chrysotile deposits. The use of all types of asbestos in the amphibole group was banned in much of the Western world by the mid-1980s, and in Japan by 1995. Some products that included amphibole types of asbestos included the following: • Low-density insulating board (often referred to as AIB or asbestos insulating board) and ceiling tiles; •
Asbestos cement sheets and pipes for construction, casing for water and electrical/telecommunication services; • Thermal and chemical insulation (e.g., fire-rated doors, limpet spray, lagging, and gaskets). • Electrical wiring, braided cables, cable wrap, wire insulation (usually
crocidolite) Cigarette manufacturer
Lorillard (
Kent's filtered cigarette) used crocidolite asbestos in its "Micronite" filter from 1952 to 1956. While mostly chrysotile asbestos fibers were once used in automobile
brake pads, shoes, and
clutch discs, contaminants of amphiboles were present. Since approximately the mid-1990s, brake pads, new or replacement, have been manufactured instead with linings made of ceramic, carbon, metallic, and
aramid fiber (
Twaron or
Kevlar—the same material used in
bulletproof vests).
Amosite Amosite, CAS No. , often referred to as brown asbestos, is a
trade name for the amphiboles belonging to the
cummingtonite-
grunerite solid solution series, commonly from South Africa, named as a partial
acronym for "Asbestos Mines of South Africa". One formula given for amosite is . Amosite is seen under a microscope as a grey-white vitreous fiber. It is found most frequently as a fire retardant in thermal insulation products,
asbestos insulating board and ceiling tiles. They are termed "asbestiform" rather than asbestos. Although the US
Occupational Safety and Health Administration (OSHA) has not included them in the asbestos standard, NIOSH and the American Thoracic Society have recommended them for inclusion as regulated materials because they may also be hazardous to health.
Construction Developed countries , for
asbestos sheeting for residential building construction The use of asbestos in new construction projects has been banned for health and safety reasons in many developed countries or regions, including the European Union, the United Kingdom, Australia, Hong Kong, Japan, and New Zealand. A notable exception is the United States, where asbestos continues to be used in construction such as cement asbestos pipes. The
5th Circuit Court prevented the EPA from banning asbestos in 1991 because EPA research showed the ban would cost between US$450 and 800 million while only saving around 200 lives in a 13-year timeframe, and that the EPA did not provide adequate evidence for the safety of alternative products. Until the mid-1980s, small amounts of white asbestos were used in the manufacture of
Artex, a decorative stipple finish, however, some of the lesser-known suppliers of Artex-type materials were still adding white asbestos until 1999. Before the ban, asbestos was widely used in the construction industry in thousands of materials. Some are judged to be more dangerous than others due to the amount of asbestos and the material's friable nature. Loose fill asbestos, sprayed coatings, pipe insulation, and
Asbestos Insulating Board (AIB) are thought to be the most dangerous due to their high content of asbestos and friable nature. Many older buildings built before the late 1990s contain asbestos. In the United States, there is a minimum standard for asbestos surveys as described by
ASTM standard E 2356–18. In the UK, the
Health and Safety Executive have issued guidance called HSG264 describing how surveys should be completed although other methods can be used if they can demonstrate they have met the regulations by other means. The EPA includes some, but not all, asbestos-contaminated facilities on the
Superfund National Priorities List (NPL). Renovation and demolition of asbestos-contaminated buildings are subject to EPA
NESHAP and OSHA Regulations. Asbestos is not a material covered under
CERCLA's innocent purchaser defense. In the UK, the removal and disposal of asbestos and substances containing it are covered by the
Control of Asbestos Regulations 2006. US asbestos consumption hit a peak of 804,000 tons in 1973; world asbestos demand peaked around 1977, with 25 countries producing nearly 4.8 million metric tons annually. In older buildings (e.g. those built before 1999 in the UK, before white asbestos was banned), asbestos may still be present in some areas. Being aware of asbestos locations reduces the risk of disturbing asbestos. Removal of asbestos building components can also remove the fire protection they provide, therefore fire protection substitutes are required for proper fire protection that the asbestos originally provided.
Outside the European Union and North America Some countries, such as
India, Indonesia, China, and Russia, have continued widespread use of asbestos. The most common is corrugated asbestos-cement sheets or "A/C sheets" for roofing and sidewalls. Millions of homes, factories, schools or sheds, and shelters continue to use asbestos. Cutting these sheets to size and drilling holes to receive 'J' bolts to help secure the sheets to roof framing is done on-site. There has been no significant change in production and use of A/C sheets in
developing countries following the widespread restrictions in developed nations.
September 11 attacks As
New York City's
World Trade Center collapsed following the
September 11 attacks,
Lower Manhattan was blanketed in a mixture of building debris and combustible materials. This complex mixture gave rise to the concern that thousands of residents and workers in the area would be exposed to known hazards in the air and dust, such as asbestos, lead, glass fibers, and pulverized concrete. More than 1,000 tons of asbestos are thought to have been released into the air following the buildings' destruction. Monitoring at and near Ground Zero immediately after the attacks indicated that the dust contained fibers, including various forms of asbestos. Inhalation of a mixture of asbestos and other toxicants is thought to be linked to the unusually high death rate from cancer of emergency service workers since the disaster. One vermiculite mine operated by
W. R. Grace and Company in
Libby, Montana exposed workers and community residents to danger by mining vermiculite contaminated with asbestos, typically
richterite, winchite,
actinolite or
tremolite. Vermiculite contaminated with asbestos from the Libby mine was used as insulation in residential and commercial buildings through Canada and the United States. W. R. Grace and Company's loose-fill vermiculite was marketed as
Zonolite but was also used in sprayed-on products such as
Monokote. In 1999, the EPA began cleanup efforts in Libby and now the area is a
Superfund cleanup area. The EPA has determined that harmful asbestos is released from the mine as well as through other activities that disturb soil in the area.
Talc made of asbestos, on a tripod over a
Teclu burner Talc can sometimes be contaminated with asbestos due to the proximity of asbestos ore (usually
tremolite) in underground talc deposits. By 1973, US federal law required all talc products to be asbestos-free. Separating
cosmetic-grade talc (e.g. talcum powder) from
industrial-grade talc (often used in friction products) has largely eliminated this issue for consumers. Cosmetics companies, including Johnson & Johnson, have known since the 1950s that talc products could be contaminated with asbestos. In July 2024, the World Health Organization (WHO) heightened its health warning about talc exposure. In a study published in The Lancet, the WHO changed its classification of talc from "possibly carcinogenic" to "probably carcinogenic." In 2000, tests in a certified asbestos-testing laboratory found the tremolite form of amphibole asbestos used to be found in three out of eight popular brands of children's
crayons that were made partly from talc:
Crayola, Prang, and RoseArt. In Crayola crayons, the tests found asbestos levels around 0.05% in
Carnation Pink and 2.86% in
Orchid; in Prang crayons, the range was from 0.3% in
Periwinkle to 0.54% in
Yellow; in Rose Art crayons, it was from 0.03% in
Brown to 1.20% in
Orange. Overall, 32 different types of crayons from these brands used to contain more than trace amounts of asbestos, and eight others contained trace amounts. The
Art and Creative Materials Institute, a
trade association which tested the safety of crayons on behalf of the makers, initially insisted the test results must have been incorrect, although they later said they do not test for asbestos. In spite of that, in June 2000 Binney & Smith, the maker of Crayola, and the other makers agreed to stop using talc in their products, and changed their product formulations in the United States. However media reports claim that the
United States Mine Safety and Health Administration (MSHA) had found asbestos in four talc samples tested in 2000. Multiple studies by mineral chemists, cell biologists, and toxicologists between 1970 and 2000 found neither samples of asbestos in talc products nor symptoms of asbestos exposure among workers dealing with talc, but more recent work has rejected these conclusions in favor of "same as" asbestos risk. On 12 July 2018, a Missouri jury ordered
Johnson & Johnson to pay a record $4.69 billion to 22 women who alleged the company's talc-based products, including its baby powder, contain asbestos and caused them to develop ovarian cancer. ==Production==