20th century In 1955,
Carl Frosch and Lincoln Derick, working at
Bell Telephone Laboratories, accidentally grew a layer of silicon dioxide over the silicon wafer, for which they observed surface passivation effects. By 1957 Frosch and Derick, using masking and predeposition, were able to manufacture silicon dioxide transistors; the first planar field effect transistors, in which drain and source were adjacent at the same surface. At Bell Labs, the importance of their discoveries was immediately realized. Memos describing the results of their work circulated at Bell Labs before being formally published in 1957. At
Shockley Semiconductor, Shockley had circulated the preprint of their article in December 1956 to all his senior staff, including
Jean Hoerni, who would later invent the
planar process in 1959 while at
Fairchild Semiconductor. In 1948, Bardeen patented an insulated-gate transistor (IGFET) with an inversion layer; Bardeen's concept forms the basis of
MOSFET technology today. An improved type of MOSFET technology,
CMOS, was developed by
Chih-Tang Sah and
Frank Wanlass at
Fairchild Semiconductor in 1963. CMOS was commercialised by
RCA in the late 1960s. Many early semiconductor device manufacturers developed and built their own equipment such as ion implanters. In 1963,
Harold M. Manasevit was the first to document epitaxial growth of
silicon on sapphire while working at the
Autonetics division of
North American Aviation (now
Boeing). In 1964, he published his findings with colleague William Simpson in the
Journal of Applied Physics. In 1965, C.W. Mueller and P.H. Robinson fabricated a MOSFET (metal–oxide–semiconductor field-effect transistor) using the silicon-on-sapphire process at
RCA Laboratories. Semiconductor device manufacturing has since spread from
Texas and
California in the 1960s to the rest of the world, including
Asia,
Europe, and the
Middle East. Wafer size has grown over time, from 25 mm (1 inch) in 1960, to 50 mm (2 inches) in 1969, 100 mm (4 inches) in 1976, 125 mm (5 inches) in 1981, 150 mm (6 inches) in 1983 and 200 mm in 1992. In the era of 2-inch wafers, these were handled manually using tweezers and held manually for the time required for a given process. Tweezers were replaced by vacuum wands as they generate fewer particles which can contaminate the wafers. Wafer carriers or cassettes, which can hold several wafers at once, were developed to carry several wafers between process steps. However, since wafers still had to be individually removed, processed, and returned, acid-resistant carriers were later introduced so the entire cassette could be dipped directly into wet etching and cleaning tanks, eliminating this time-consuming process. When wafer sizes increased to 100 mm, the entire cassette would often not be dipped as uniformly, and the quality of the results across the wafer became hard to control. By the time 150 mm wafers arrived, the cassettes were not dipped and were only used as wafer carriers and holders to store wafers, and robotics became prevalent for handling wafers. With 200 mm wafers, manual handling of wafer cassettes becomes risky as they are heavier. In the 1970s and 1980s, several companies migrated their semiconductor manufacturing technology from
bipolar to MOSFET technology. Semiconductor manufacturing equipment has been considered costly since 1978. In 1984,
KLA developed the first automatic reticle and photomask inspection tool. In 1985, KLA developed an automatic inspection tool for silicon wafers, which replaced manual microscope inspection. In 1985, SGS (now
STmicroelectronics) invented BCD, also called
BCDMOS, a semiconductor manufacturing process using bipolar, CMOS and
DMOS devices.
Applied Materials developed the first practical multi-chamber, or cluster wafer processing tool, the Precision 5000. Until the 1980s, physical vapor deposition was the primary technique used for depositing materials onto wafers, until the advent of chemical vapor deposition. Equipment with diffusion pumps was replaced with those using
turbomolecular pumps, as the latter do not use oil, which often contaminates wafers during processing in vacuum. 200 mm diameter wafers were first used in 1990 and became the standard until the introduction of 300 mm diameter wafers in 2000. Bridge tools were used in the transition from 150 mm wafers to 200 mm wafers and in the transition from 200 mm to 300 mm wafers. The semiconductor industry has adopted larger wafers to cope with the increased demand for chips as larger wafers provide more surface area per wafer. Over time, the industry shifted to 300 mm wafers which brought along the adoption of FOUPs, but many products that are not advanced are still produced in 200 mm wafers such as analog ICs, RF chips, power ICs, BCDMOS and
MEMS devices. Some processes such as cleaning, ion implantation, etching, annealing and oxidation started to adopt single wafer processing instead of batch wafer processing to improve the reproducibility of results. A similar trend existed in MEMS manufacturing. In 1998, Applied Materials introduced the Producer, a cluster tool that had chambers grouped in pairs for processing wafers, which shared common vacuum and supply lines but were otherwise isolated, which was revolutionary at the time as it offered higher productivity than other cluster tools without sacrificing quality, due to the isolated chamber design. They also have facilities spread in different countries. As the average utilization of semiconductor devices increased, durability became an issue and manufacturers started to design their devices to ensure they last for enough time, and this depends on the market the device is designed for. This especially became a problem at the 10 nm node.
Silicon on insulator (SOI) technology has been used in
AMD's 130 nm, 90 nm, 65 nm, 45 nm and 32 nm single, dual, quad, six and eight core processors made since 2001. During the transition from 200 mm to 300 mm wafers in 2001, many bridge tools were used which could process both 200 mm and 300 mm wafers. At the time, 18 companies could manufacture chips in the leading edge 130 nm process. In 2006, 450 mm wafers were expected to be adopted in 2012, and 675 mm wafers were expected to be used by 2021. Since 2009, "node" has become a commercial name for marketing purposes that indicates new generations of process technologies, without any relation to gate length, metal pitch or gate pitch. For example,
GlobalFoundries'
7 nm process was similar to Intel's
10 nm process, thus the conventional notion of a process node has become blurred. Additionally, TSMC and Samsung's 10 nm processes are only slightly denser than Intel's 14 nm in transistor density. They are actually much closer to Intel's 14 nm process than they are to Intel's 10 nm process (e.g. Samsung's 10 nm processes' fin pitch is the same as that of Intel's 14 nm process: 42 nm). Intel has changed the name of its 10 nm process to position it as a 7 nm process. As transistors become smaller, new effects start to influence design decisions, such as self-heating of the transistors, and other effects, such as electromigration, have become more evident since the 16nm node. In 2011,
Intel demonstrated
Fin field-effect transistors (FinFETs), where the gate surrounds the channel on three sides, allowing for increased energy efficiency and lower gate delay—and thus greater performance—over planar transistors at the 22 nm node, because planar transistors which only have one surface acting as a channel, started to suffer from short channel effects. A startup called SuVolta created a technology called Deeply Depleted Channel (DDC) to compete with FinFET transistors; it uses very lightly doped planar transistors at the 65 nm node. By 2018, a number of transistor architectures had been proposed for the eventual replacement of
FinFET, most of which were based on the concept of
GAAFET: horizontal and vertical nanowires, horizontal nanosheet transistors (Samsung MBCFET, Intel Nanoribbon), vertical FET (VFET) and other vertical transistors, complementary FET (CFET), stacked FET, vertical TFETs, FinFETs with III-V semiconductor materials (III-V FinFET), several kinds of horizontal gate-all-around transistors such as nano-ring, hexagonal wire, square wire, and round wire gate-all-around transistors and negative-capacitance FET (NC-FET) which uses drastically different materials. FD-SOI was seen as a potential low cost alternative to FinFETs. As of 2019,
14 nm process and
10 nm process chips are in mass production by Intel,
UMC, TSMC, Samsung,
Micron,
SK Hynix,
Toshiba Memory and GlobalFoundries, with
7 nm process chips in mass production by TSMC and Samsung, although their 7 nm node definition is similar to Intel's 10 nm process. The
5 nm process began being produced by Samsung in 2018. As of 2019, the node with the highest
transistor density is TSMC's 5nm N5 node, with a density of 171.3million transistors per square millimeter. In 2019, Samsung and TSMC announced plans to produce
3 nm process nodes. GlobalFoundries has decided to stop the development of new nodes beyond 12 nm to save resources, as it has determined that setting up a new fab to handle sub-12 nm orders would be beyond the company's financial abilities. From 2020 to 2023, there was a
global chip shortage. During this shortage caused by the COVID-19 pandemic, many semiconductor manufacturers banned employees from leaving company grounds. Many countries granted subsidies to semiconductor companies for building new fabrication plants or fabs. Many companies were affected by counterfeit chips. Semiconductors have become vital to the world economy and the national security of some countries. The US has asked TSMC to not produce semiconductors for Huawei, a Chinese company. CFET transistors were explored, which stacks NMOS and PMOS transistors on top of each other. Two approaches were evaluated for constructing these transistors: a monolithic approach which built both types of transistors in one process, and a sequential approach which built the two types of transistors separately and then stacked them. ==List of steps==