Alloys The following casting alloys are mostly used for making crowns, bridges and dentures.
Titanium, usually commercially pure but sometimes a 90% alloy, is used as the anchor for
dental implants as it is
biocompatible and can integrate into bone. ;Precious metallic alloys •
gold (high purity: 99.7%) •
gold alloys (with high gold content) • gold-platina alloy • silver-palladium alloy ;Base metallic alloys •
cobalt-chrome alloy •
nickel-chrome alloy
Amalgam Amalgams are alloys formed by a reaction between two or more metals, one of which is
mercury. It is a hard restorative material and is silvery-grey in colour. One of the oldest direct restorative materials still in use, dental amalgam was widely used in the past with a high degree of success, although recently its popularity has declined due to a number of reasons, including the development of alternative bonded restorative materials, increase in demand for more aesthetic restorations and public perceptions concerning the potential health risks of the material. The composition of dental amalgam is controlled by the ISO Standard for dental amalgam alloy (ISO 1559). Inorganic filler such as
silica, quartz or various glasses, are added to reduce
polymerization shrinkage by occupying volume and to confirm radio-opacity of products due to translucency in property, which can be helpful in diagnosis of dental caries around dental restorations. The filler particles give the composites
wear resistance as well. Compositions vary widely, with proprietary mixes of resins forming the matrix, as well as engineered filler glasses and glass ceramics. A coupling agent such as
silane is used to enhance the bond between resin matrix and filler particles. An initiator package begins the polymerization reaction of the resins when external energy (light/heat, etc.) is applied. For example, camphorquinone can be excited by visible blue light with critical wavelength of 460-480 nm to yield necessary free radicals to start the process. After
tooth preparation, a thin primer or bonding agent is used. Modern
photo-polymerised composites are applied and cured in relatively thin layers as determined by their opacity. After some curing, the final surface will be shaped and polished.
Glass ionomer cement A
glass ionomer cement (GIC) is a class of materials commonly used in dentistry as direct filling materials and/or for luting indirect restorations. GIC can also be placed as a lining material in some restorations for extra protection. These tooth-coloured materials were introduced in 1972 for use as restorative materials for anterior teeth (particularly for eroded areas). The desirable properties of glass ionomer cements make them useful materials in the restoration of carious lesions in low-stress areas such as smooth-surface and small anterior proximal cavities in primary teeth. Advantages of using glass ionomer cement: Compomers were formed by modifying dental composites with poly-acid in an effort to combine the desirable properties of dental composites, namely their good aesthetics, and glass ionomer cements, namely their ability to release fluoride over a long time. Whilst this combination of good aesthetics and fluoride release may seem to give compomers a selective advantage, their poor mechanical properties (detailed below) limits their use. Some of the materials used are
glass-bonded porcelain (Vitablock),
lithium disilicate glass-ceramic (a ceramic crystallizing from a glass by special heat treatment), and phase stabilized
zirconia (zirconium dioxide, ZrO2). Previous attempts to utilize high-performance ceramics such as zirconium-oxide were thwarted by the fact that this material could not be processed using the traditional methods used in dentistry. Because of its high strength and comparatively much higher fracture toughness, sintered zirconium oxide can be used in posterior crowns and bridges, implant abutments, and root dowel pins. Lithium disilicate (used in the latest Chairside Economical Restoration of Esthetic Ceramics
CEREC product) also has the fracture resistance needed for use on molars. Some all-ceramic restorations, such as porcelain-fused-to-alumina set the standard for high aesthetics in dentistry because they are strong and their color and translucency mimic natural tooth enamel. Cast metals and porcelain-on-metal were the standard material for crowns and bridges for long time. The full ceramic restorations are now the major choice of patients and are of commonly applied by dentists.
Comparison • Composites and amalgam are used mainly for direct restoration. Composites can be made of color matching the tooth, and the surface can be polished after the filling procedure has been completed. • Amalgam fillings expand with age, possibly cracking the tooth and requiring repair and filling replacement, but chance of leakage of filling is less. • Composite fillings shrink with age and may pull away from the tooth allowing leakage. If leakage is not noticed early, recurrent decay may occur. • A 2003 study showed that fillings have a finite lifespan: an average of 12.8 years for amalgam and 7.8 years for composite resins. Fillings fail because of changes in the filling, tooth or the bond between them. Secondary cavity formation can also affect the structural integrity the original filling. Fillings are recommended for small to medium-sized restorations. • Inlays and onlays are more expensive indirect restoration alternative to direct fillings. They are supposed to be more durable, but long-term studies did not always detect a significantly lower failure rate of ceramic or composite inlays compared to composite direct fillings. • Porcelain, cobalt-chrome, and gold are used for indirect restorations like crowns and partial coverage crowns (onlays). Traditional porcelains are brittle and are not always recommended for
molar restorations. Some hard porcelains cause excessive wear on opposing teeth.
Experimental The US National Institute of Dental Research and international organizations as well as commercial suppliers conduct research on new materials. In 2010, researchers reported that they were able to stimulate mineralization of an enamel-like layer of
fluorapatite in vivo. Filling material that is compatible with pulp tissue has been developed; it could be used where previously a root canal or extraction was required, according to 2016 reports. == Restoration using dental implants ==