of a woman fixing her hair using a mirror, from
Stabiae, Italy, 1st century AD ,
Bruges, 1434 AD copy of an original by
Chinese painter Gu Kaizhi, , India, in the 12th century
Prehistory The first mirrors used by humans were most likely pools of still water, or shiny stones. The requirements for making a good mirror are a surface with a very high degree of
flatness (preferably but not necessarily with high
reflectivity), and a
surface roughness smaller than the wavelength of the light. The earliest manufactured mirrors were pieces of polished stone such as
obsidian, a naturally occurring
volcanic glass. In China,
bronze mirrors were manufactured from around 2000 BC, some of the earliest bronze and copper examples being produced by the
Qijia culture. Such metal mirrors remained the norm through to
Greco-Roman Antiquity and throughout the
Middle Ages in
Europe. During the
Roman Empire silver mirrors were in wide use by servants.
Speculum metal is a highly reflective
alloy of copper and
tin that was used for mirrors until a couple of centuries ago. Such mirrors may have originated in China and India. Mirrors of speculum metal or any precious metal were hard to produce and were only owned by the wealthy. Common metal mirrors tarnished and required frequent polishing. Bronze mirrors had low reflectivity and poor
color rendering, and stone mirrors were much worse in this regard. These defects explain the
New Testament reference in
1 Corinthians 13 to seeing "as in a mirror, darkly." The
Greek philosopher Socrates urged young people to look at themselves in mirrors so that, if they were beautiful, they would become worthy of their beauty, and if they were ugly, they would know how to hide their disgrace through learning.
Glass began to be used for mirrors in the 1st century
CE, with the development of
soda-lime glass and
glass blowing. The Roman scholar
Pliny the Elder claims that artisans in
Sidon (modern-day
Lebanon) were producing glass mirrors coated with
lead or
gold leaf in the back. The metal provided good reflectivity, and the glass provided a smooth surface and protected the metal from scratches and tarnishing. However, there is no archeological evidence of glass mirrors before the third century. These early glass mirrors were made by blowing a glass bubble, and then cutting off a small circular section from 10 to 20
cm in diameter. Their surface was either concave or convex, and imperfections tended to distort the image. Lead-coated mirrors were very thin to prevent cracking by the heat of the molten metal. Due to the poor quality, high cost, and small size of glass mirrors, solid-metal mirrors (primarily of steel) remained in common use until the late nineteenth century. Silver-coated metal mirrors were developed in China as early as 500 CE. The bare metal was coated with an
amalgam, then heated until the
mercury boiled away.
Middle Ages and Renaissance mirror in the
Musée des Arts décoratifs, Strasbourg in eastern
Xi'an The evolution of glass mirrors in the
Middle Ages followed improvements in
glassmaking technology. Glassmakers in
France made flat glass plates by blowing glass bubbles, spinning them rapidly to flatten them, and cutting rectangles out of them. A better method, developed in
Germany and perfected in
Venice by the 16th century, was to blow a cylinder of glass, cut off the ends, slice it along its length, and unroll it onto a flat hot plate. Venetian glassmakers also adopted
lead glass for mirrors, because of its crystal-clarity and its easier workability. During the early European
Renaissance, a
fire-gilding technique developed to produce an even and highly reflective
tin coating for glass mirrors. The back of the glass was coated with a tin–mercury
amalgam, and the mercury was then evaporated by heating the piece. This process caused less
thermal shock to the glass than the older molten-lead method. The date and location of the discovery is unknown, but by the 16th century Venice was a center of mirror production using this technique. These Venetian mirrors were up to square. Venice retained its monopoly on the tin amalgam technique for a century. Venetian mirrors in richly decorated frames served as luxury decorations for palaces throughout Europe, and were very expensive. For example, in the late seventeenth century, the Countess de Fiesque was reported to have traded an entire wheat farm for a mirror, considering it a bargain. However, by the end of that century the secret was leaked through industrial espionage. French workshops succeeded in large-scale industrialization of the process, eventually making mirrors affordable to the masses, in spite of the
toxicity of mercury's vapor.
Industrial Revolution The invention of the
ribbon machine in the late
Industrial Revolution allowed modern glass panes to be produced in bulk. The
Saint-Gobain factory, founded by royal initiative in France, was an important manufacturer, and
Bohemian and German glass, often rather cheaper, was also important. The invention of the
silvered-glass mirror is credited to German chemist
Justus von Liebig in 1835. His
wet deposition process involved the deposition of a thin layer of metallic silver onto glass through the chemical reduction of
silver nitrate. This silvering process was adapted for mass manufacturing and led to the greater availability of affordable mirrors.
Contemporary technologies Mirrors are often produced by the wet deposition of silver, or sometimes nickel or chromium (the latter used most often in automotive mirrors) via
electroplating directly onto the glass substrate. Glass mirrors for optical instruments are usually produced by
vacuum deposition methods. These techniques can be traced to observations in the 1920s and 1930s that metal was being ejected from
electrodes in
gas discharge lamps and condensed on the glass walls forming a mirror-like coating. The phenomenon, called
sputtering, was developed into an industrial metal-coating method with the development of
semiconductor technology in the 1970s. A similar phenomenon had been observed with
incandescent light bulbs: the metal in the hot filament would slowly
sublimate and condense on the bulb's walls. This phenomenon was developed into the method of
evaporation coating by Pohl and Pringsheim in 1912.
John D. Strong used evaporation coating to make the first
aluminium-coated telescope mirrors in the 1930s. The first
dielectric mirror was created in 1937 by Auwarter using evaporated
rhodium. The metal coating of glass mirrors is usually protected from abrasion and corrosion by a layer of paint applied over it. Mirrors for optical instruments often have the metal layer on the front face, so that the light does not have to cross the glass twice. In these mirrors, the metal may be protected by a thin transparent coating of a non-metallic (
dielectric) material. The first metallic mirror to be enhanced with a dielectric coating of
silicon dioxide was created by Hass in 1937. In 1939 at the
Schott Glass company, Walter Geffcken invented the first dielectric mirrors to use multilayer coatings.
Burning mirrors The
Greek in
Classical Antiquity were familiar with the use of mirrors to concentrate light.
Parabolic mirrors were described and studied by the mathematician
Diocles in his work
On Burning Mirrors.
Ptolemy conducted a number of experiments with curved polished iron mirrors, and discussed plane, convex spherical, and concave spherical mirrors in his
Optics. Parabolic mirrors were also described by the
Caliphate mathematician
Ibn Sahl in the tenth century. ==Types of mirrors==