Formation in south-western Spain. led the purchase of the Rio Tinto mines from Spain, and was the company's first president. Since antiquity, a site along the
Río Tinto in
Huelva, Spain, has been mined for copper, silver, gold and other minerals. Around 3000 BC,
Iberians and
Tartessians began mining the site, followed by the
Phoenicians,
Greeks,
Romans,
Visigoths and
Moors. After a period of abandonment, the mines were rediscovered in 1556 and the Spanish government began operating them once again in 1724. leading the government to sell the mines in 1873 at a price later determined to be well below actual value. The purchasers of the mine were led by
Hugh Matheson's
Matheson & Company, which ultimately formed a syndicate consisting of
Deutsche Bank (56% ownership), Matheson (24%) and the civil engineering firm Clark, Punchard and Company (20%). At an auction held by the Spanish government to sell the mine on 14 February 1873, the group won with a bid of
£3.68 million (
ESP 92.8 million). The bid also specified that Spain would permanently relinquish any right to claim
royalties on the mine's production. Following purchase of the mine, the syndicate launched the Rio Tinto Company, registering it on 29 March 1873. The toxic fumes released by this process had a negative impact on the farmland and the local agriculturists, which led to the company's workers and some local
anarchists coming together to protest against this practice. On 4 February 1888, several thousand rank and file—agriculturalists, anarchists and mineworkers—marched to the Río Tinto town hall (
ayuntamiento) to deliver their petitions to the mayor. The civil guards, under perceived threat of mob violence,
fired on the crowd, killing at least 13 and injuring 35. From 1877 to 1891, the Río Tinto Mine was the world's leading producer of copper. mine was part of Rio Tinto's original operations in Spain. From 1870 through 1925, the company was inwardly focused on fully exploiting the Río Tinto Mine, with little attention paid to expansion or exploration activities outside of Spain. The company enjoyed strong financial success until 1914,
colluding with other pyrite producers to control market prices. However, World War I and its aftermath effectively eliminated the United States as a viable market for European
pyrites, leading to a decline in the firm's prominence. Rio Tinto's investment in Rhodesian copper mines did much to support the company through troubled times at its Spanish Rio Tinto operations spanning the
Spanish Civil War,
World War II and
Franco's nationalistic policies. In the 1950s, the political situation made it increasingly difficult for mostly British and French owners to extract profits from Spanish operations, and the company decided to dispose of the mines from which it took its name. The sale of the mines financed extensive exploration activities over the following decade. The company's exploration activities presented the company with an abundance of opportunities, but it lacked sufficient capital and operating revenue to exploit those opportunities. This situation precipitated the next, and perhaps most significant, merger in the company's history. In 1962, Rio Tinto Company merged with the Australian firm
Consolidated Zinc to form the Rio Tinto – Zinc Corporation (RTZ) and its main subsidiary, Conzinc Riotinto of Australia (CRA). The merger provided Rio Tinto the ability to exploit its new-found opportunities, and gave Consolidated Zinc a much larger asset base. The other cartel members were based in Australia, France, and South Africa. In 2000, Rio Tinto acquired
North Limited, an Australian company with iron ore and
uranium mines, for $2.8 billion. The takeover was partially motivated as a response to North Limited's 1999 bid to have Rio Tinto's
Pilbara railway network declared
open access. The
Australian Competition & Consumer Commission regulatory body approved the acquisition in August 2000, and the purchase was completed in October of the same year. That year, Rio Tinto also bought North Limited and Ashton Mining for US$4 billion, adding additional resources in aluminium, iron ore, diamonds and coal. On 14 November 2007, Rio Tinto completed its largest acquisition to date, , "the largest mining deal ever completed". Activity in 2008 and 2009 was focused on divestments of assets to raise cash and refocus on core business opportunities. The company sold three major assets in 2008, raising about $3 billion in cash. In the first quarter of 2009, Rio Tinto reached agreements to sell its interests in the
Corumbá iron ore mine and the
Jacobs Ranch coal mine, and completed sales of an aluminium smelter in China and the company's
potash operations, for an additional estimated $2.5 billion. One of the arrested, Australian citizen
Stern Hu, was "suspected of stealing Chinese state secrets for foreign countries and was detained on criminal charges", according to a spokesman for the Chinese foreign ministry. Stern Hu was also accused of bribery by Chinese steel mill executives for sensitive information during the iron ore contract negotiations. In 2009, Chinese authorities began investigating allegations against Rio Tinto in what became known as the
Rio Tinto espionage case. These included bribing executives from 16 of China's biggest steel mill companies to get hold of secret information. On 29 March 2010 four Rio Tinto employees including Australian citizen
Stern Hu were found guilty of these charges and of accepting millions of dollars in bribes. They were ordered to pay hundreds of thousands of dollars in fines, and sentenced to 7 to 14 years in jail. On 19 March 2010 Rio Tinto and its biggest shareholder,
Chinalco, signed a memorandum of understanding to develop Rio Tinto's iron ore project in the
Simandou mine in
Simandou,
Guinea. On 29 July 2010, Rio Tinto and Chinalco signed a binding agreement to establish this
joint venture covering the development and operation of the Simandou mine. The remaining 5% would be owned by the
International Finance Corporation (IFC), the financing arm of the
World Bank. On 22 April 2011 Rio Tinto, its subsidiary Simfer S.A. (Simfer), and the Guinean Government signed a settlement agreement that secured Rio Tinto's mining rights in Guinea to the southern concession of Simandou, known as blocks 3 and 4. According to the agreement, Simfer would pay US$700 million and receive mining concession and government approval of the proposed Chalco and Rio Tinto Simandou joint venture. The
Securities & Exchange Commission investigated a $3 billion impairment charge against Rio Tinto regarding the deal. Riversdale Mining was an Australian
coal mining company with significant interests in Mozambique. Rio Tinto bought it for $2.9 billion in an all-cash deal. Two years later they wrote down the value of the assets by $3 billion. Following the impairment charge, which included an additional $11 billion in asset write-downs, chief executive officer of Rio Tinto, Tom Albanese stepped down from his post and left the company. Rio later sold the assets for $50 million. On 13 December 2011, an independent arbitrator cleared the way for Rio Tinto, which had owned 49% of Ivanhoe Mines (now known as
Turquoise Hill Resources), to take it over: he said the $16 billion Canadian group's "
poison pill" defence was not valid. Ivanhoe had developed
Oyu Tolgoi in Mongolia, one of the world's largest-known copper deposits. On 28 January 2012, Rio Tinto gained control of Ivanhoe Mines and removed the management. of Rio Tinto's subsidiary, Kennecott Utah Copper The metals for the medals for the
2012 Summer Olympics were supplied from the
Bingham Canyon Mine located in Utah and the
Oyu Tolgoi mine in Mongolia, which caused uproar among many activist groups, especially in Utah due to their concern about the impact to the local cities. One person particularly bothered by this decision was the Commissioner of the London Games, Meredith Alexander, who quit her position and led a coalition of human rights and environmental groups during the "Greenwashed Gold Campaign". In October 2013, Rio Tinto agreed to sell its majority stake in Australia's third-largest coal mine to
Glencore and
Sumitomo for a little over US$1 billion, as part of the firm's plans to focus on larger operations. Less than a year later, Rio Tinto rejected two merger proposals from Glencore, proffered in July and August 2014; the merger of Glencore and Rio Tinto would have created the world's largest mining company. In October 2015, Rio Tinto was criticised by the Guinean government for the many mining delays at the local
Simandou mine. Cece Noramou, government official said the government was "running out of patience". President Alpha Conde himself said that "there have been people at Simandou for 15 years, 20 years, and they've never produced a ton of iron". Even before 2015, the Guinean government had expressed their displeasure and dissatisfaction with Rio Tinto; in 2008, the Guinean government annulled half of the company's Simandou rights and gave them to BSGR, a French–Israeli-owned mining company. In late 2016, Rio Tinto agreed to sell its stake in the Simandou iron ore mine to Chinalco and exit the deal. The deal was negotiated after the company's case against Vale and BSGR was dismissed at US District Court. In 2016, Rio Tinto became embroiled in a number of corruption allegations over its acquisition of stakes in the Simandou iron ore mine in Guinea. The allegations centre around the payment of a $10.5 million bribe to , a French banking consultant who was a friend and adviser of President
Alpha Condé. Condé denied having any knowledge of the illegal transactions, but recordings obtained by France24 suggest otherwise. Also in early November 2016, the former mining minister of Guinea, Mahmoud Thiam, revealed that the head of Rio Tinto's operation in Guinea offered him a bribe in 2010 to win back control of the Simandou mine, and that his offer was supported by senior members of the company. In July 2017 the Serious Fraud Office announced the launch of a fraud and corruption investigation into the company's business practices in Guinea. The
Australian Federal Police is also investigating the allegations. After the Serious Fraud Office investigation announcement, and amid a search for a new CEO, Rio director John Varley was forced to resign from his role in the company. On 6 March 2023, the US SEC announced charges against Rio Tinto plc for violations of the Foreign Corrupt Practices Act (FCPA) arising out of a bribery scheme involving a consultant in Guinea. The company agreed to pay a $15 million civil penalty to settle the SEC's charges. In May 2020, to expand the
Brockman 4 mine, Rio Tinto demolished an
Australian Aboriginal sacred site in
Juukan Gorge, Western Australia, which had evidence of 46,000 years of continual human occupation, and was considered the only inland prehistoric site in Australia to show signs of continual human occupation through the last
Ice Age. The company later revealed it had three alternative options to preserve the site, but chose to destroy it without informing the
traditional owners of the alternatives. Permission to destroy the site had been given in 2013 under the state
Aboriginal Heritage Act 1972, which, however, has been under review since 2018. The
Puutu Kunti Kurrama and
Pinikura peoples, who are the local land custodians, had fought the decision. The destruction brought widespread criticism. On 31 May, Rio Tinto apologised for the distress caused. On 11 September 2020, it was announced that, as a result of the destruction at Juukan Gorge, CEO
Jean-Sébastien Jacques and two other Rio Tinto executives would step down. The company's chief financial officer,
Jakob Stausholm, became the new chief executive on 1 January 2021. During 2021, a
series of mass protests broke out in Serbia against the construction of a
lithium mine in Western Serbia by the Rio Tinto corporation. Protesters blocked major roads and bridges in Belgrade and other major cities. In the town of
Šabac, there was an incident when a member of the ruling party attacked the protesters with an excavator, and then the protesters were beaten by an armed group of hooligans. The project would make Serbia the biggest producer of lithium globally, and provide raw materials to more than 1 million electric cars. In June 2024, the constitutional court reverted the government's decision to remove Rio Tinto from the project, and the president of Serbia announced that he was expecting the company to reveal their final plans for the mine in July and that the mine might be built by 2028. In February 2022, Rio Tinto released a report that described a work culture of bullying, harassment and racism, including twenty one complaints by women of actual or attempted rape or sexual assault in the past five years. According to the report, these harmful behaviours were often tolerated or normalised. "Harmful behaviour by serial perpetrators is often an open secret", Elizabeth Broderick said. On the whole, about 28% of women and 7% of men had experienced sexual harassment at Rio. But this rate rose to 41% for female workers at
FIFO sites. Most women who responded had experienced "everyday sexism". In March 2022, Rio Tinto completed the acquisition of Rincon Mining's
lithium project in Argentina for $825 million, following approval by Australia's
Foreign Investment Review Board. In January 2023, the company announced that it had
misplaced a capsule of radioactive material that was being transported from their Gudai-Darri mine in Western Australia. The capsule is a 8 by 6 mm cylinder containing a 19-gigabecquerel
caesium-137 ceramic source. It has the capability of causing serious illness if it is not handled correctly. According to the company, the capsule was lost somewhere between
Newman and
Perth, a distance of 1,400 km. The company launched an investigation into the disappearance and are working alongside authorities. Later the same month the capsule was recovered by investigators and verified by the
Australian Defence Forces. In July 2023, it was announced Rio Tinto had acquired a 15 per cent stake in the Australian exploration and development company, Sovereign Metals for US $27.6 million. In October 2024, Rio Tinto announced it would buy
Arcadium Lithium for US$6.7 billion, in an all-cash deal for US$5.85 per each Arcadium Lithium share. The deal was closed in March 2025, with Arcadium Lithium becoming Rio Tinto's lithium unit, called Rio Tinto Lithium. With the purchase of Arcadium, Rio Tinto became the world's third largest lithium miner. The
Biden administration's regulation, completed in May 2024, required the only two copper smelters in the United States to reduce emissions of toxic pollutants such as
lead,
arsenic,
mercury,
benzene and
dioxins. Shortly after
beginning his second presidency, Trump classified
copper as a strategically important raw material for defence, infrastructure and new technologies by decree and on 24 October 2025 suspended the regulation for two years. The
US Department of Energy (DOE) has since been tasked with developing a plan to reduce emissions from copper smelters. In May 2025, it was announced that Rio Tinto was partnering with Chilean
state-owned Codelco for a
lithium mine in northern Chile. The deal makes Rio Tinto the third private company to mine lithium in Chile. The company will invest $900 million and own just under half of the operation. In August the same year Rio Tinto announced a partnership with Chilean state-owned
ENAMI to carry out the lithium project Salares Altoandinos in
Atacama Region. On 22 May 2025, the company announced its chief executive Jakob Stausholm will step down later in the year once it has selected his replacement. In July 2025, Rio Tinto announced the appointment of Simon Trott as its new chief executive, due to assume the role on 25 August 2025. Trott has been at the company for more than 20 years most recently leading its
iron ore unit. == Subsidiaries ==