The conversion of dead vegetation into coal is called
coalification. At various times in the geologic past, the Earth had dense forests in low-lying areas. In these wetlands, the process of coalification began when dead plant matter was protected from
oxidation, usually by mud or acidic water, and was converted into
peat. The resulting
peat bogs, which trapped immense amounts of carbon, were eventually deeply buried by sediments. Then, over millions of years, the heat and pressure of deep burial caused the loss of water,
methane and carbon dioxide and increased the proportion of carbon. The grade of coal produced depended on the maximum pressure and temperature reached, with
lignite (also called "brown coal") produced under relatively mild conditions, and
sub-bituminous coal,
bituminous coal, or
anthracite coal (also called "hard coal" or "black coal") produced in turn with increasing temperature and pressure. Of the factors involved in coalification, temperature is much more important than either pressure or time of burial. Subbituminous coal can form at temperatures as low as while anthracite requires a temperature of at least . Although coal is known from most geologic
periods, 90% of all coal beds were deposited in the
Carboniferous and
Permian periods. Paradoxically, this was during the
Late Paleozoic icehouse, a time of global
glaciation. However, the drop in global sea level accompanying the glaciation exposed
continental shelves that had previously been submerged, and to these were added wide
river deltas produced by increased
erosion due to the drop in
base level. These widespread areas of wetlands provided ideal conditions for coal formation. The rapid formation of coal ended with the
coal gap in the
Permian–Triassic extinction event, where coal is rare. Favorable geography alone does not explain the extensive Carboniferous coal beds. Other factors contributing to rapid coal deposition were high
oxygen levels, above 30%, that promoted intense
wildfires and formation of
charcoal that was all but indigestible by decomposing organisms; high
carbon dioxide levels that promoted plant growth; and the nature of Carboniferous forests, which included
lycophyte trees whose
determinate growth meant that carbon was not tied up in
heartwood of living trees for long periods. One theory suggested that about 360 million years ago, some plants evolved the ability to produce
lignin, a complex polymer that made their
cellulose stems much harder and more woody. The ability to produce lignin led to the evolution of the first
trees. But bacteria and fungi did not immediately evolve the ability to decompose lignin, so the wood did not fully decay but became buried under sediment, eventually turning into coal. About 300 million years ago, mushrooms and other fungi developed this ability, ending the main coal-formation period of earth's history. Although some authors pointed at some evidence of lignin degradation during the Carboniferous, and suggested that climatic and tectonic factors were a more plausible explanation, reconstruction of ancestral enzymes by phylogenetic analysis corroborated a hypothesis that lignin degrading enzymes appeared in fungi approximately 200 MYa. One likely tectonic factor was the
Central Pangean Mountains, an enormous range running along the equator that reached its greatest elevation near this time. Climate modeling suggests that the Central Pangean Mountains contributed to the deposition of vast quantities of coal in the late Carboniferous. The mountains created an area of year-round heavy precipitation, with no dry season typical of a
monsoon climate. This is necessary for the preservation of peat in coal swamps. Coal is known from
Precambrian strata, which predate land plants. This coal is presumed to have originated from residues of algae. Sometimes coal seams (also known as coal beds) are interbedded with other sediments in a
cyclothem. Cyclothems are thought to have their origin in
glacial cycles that produced fluctuations in
sea level, which alternately exposed and then flooded large areas of continental shelf.
Chemistry of coalification The woody tissue of plants is composed mainly of cellulose, hemicellulose, and lignin. Modern peat is mostly lignin, with a content of cellulose and hemicellulose ranging from 5% to 40%. Various other organic compounds, such as waxes and nitrogen- and sulfur-containing compounds, are also present. Lignin has a weight composition of about 54% carbon, 6% hydrogen, and 30% oxygen, while cellulose has a weight composition of about 44% carbon, 6% hydrogen, and 49% oxygen. Bituminous coal has a composition of about 84.4% carbon, 5.4% hydrogen, 6.7% oxygen, 1.7% nitrogen, and 1.8% sulfur, on a weight basis. The low oxygen content of coal shows that coalification removed most of the oxygen and much of the hydrogen a process called
carbonization. Carbonization proceeds primarily by
dehydration,
decarboxylation, and demethanation. Dehydration removes water molecules from the maturing coal via reactions such as :2 R–OH → R–O–R + H2O
Decarboxylation removes carbon dioxide from the maturing coal: The effect of decarboxylation is to reduce the percentage of oxygen, while demethanation reduces the percentage of hydrogen. Dehydration does both, and (together with demethanation) reduces the saturation of the carbon backbone (increasing the number of double bonds between carbon). As carbonization proceeds,
aliphatic compounds convert to
aromatic compounds. Similarly, aromatic rings fuse into
polyaromatic compounds (linked rings of carbon atoms). The structure increasingly resembles
graphene, the structural element of graphite. Chemical changes are accompanied by physical changes, such as decrease in average pore size.
Macerals Macerals are coalified plant parts that retain the morphology and some properties of the original plant. In many coals, individual macerals can be identified visually. Some macerals include: Maturation of bituminous coal is characterized by
bitumenization, in which part of the coal is converted to
bitumen, a hydrocarbon-rich gel. Maturation to anthracite is characterized by
debitumenization (from demethanation) and the increasing tendency of the anthracite to break with a
conchoidal fracture, similar to the way thick glass breaks.
Types As geological processes apply
pressure to dead
biotic material over time, under suitable conditions, its
metamorphic grade or rank increases successively into: •
Peat, a precursor of coal •
Lignite, or brown coal, the lowest rank of coal, most harmful to health when burned, The classification of coal is generally based on the content of
volatiles. However the most important distinction is between thermal coal (also known as steam coal), which is burnt to generate electricity via steam; and
metallurgical coal (also known as coking coal), which is burnt at high temperature to make
steel.
Hilt's law is a geological observation that (within a small area) the deeper the coal is found, the higher its rank (or grade). It applies if the thermal gradient is entirely vertical; however,
metamorphism may cause lateral changes of rank, irrespective of depth. For example, some of the coal seams of the
Madrid, New Mexico coal field were partially converted to anthracite by
contact metamorphism from an igneous
sill while the remainder of the seams remained as bituminous coal. ==History==